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is used here, where


МЕХЛв[{Ра}] = У *Φ[nθ(r)]∙

(4.5)


Φ[nct(r)] is given by

ɪ г 1 ι∕ι ∖ ∣ ^,1^2           ^,2          Tlυl∙Tlv2 7⅛(τ⅛2∙^⅛2) z. c

ФЫ = -no ɪn(l - n3) ++ 24πtl _ Пз)2 -      - 8я(1_„з)г. (4.6)

and na are the weighted densities. The long range attraction is included using the
mean field approximation.

- Ilb Ilb n

Aex^t[{pa}] = ^Yι         ⅛*2<≈(r2-rl)p∞<(r1)p∞>(r2).  (4.7)

a=l 7=1 ∙'∣Γ2-Γ1∣>σα.y

Aex,assoc can ɪɔθ writtθn following TPTl using the extension (to fluid mixtures
with molecules having multiple bonding sites) and general notation of Chapman [58,
62] as,

Mfx'ωηW] = ∕⅛ιf>s<*(rι) £ ɑnjɑ(n) -
j α=l         
AΓ<q) '


(4.8)


The first summation is over all the segments α, and the second over all the association
sites on segment
a where f(ɑɔ is the set of all the associating sites on segment а. Хд
denotes the fraction of segments of type a which are not bonded at their site A. This

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