he Effect of Phosphorylation on the Electron Capture Dissociation of Peptide Ions



Creese and Cooper


Page 14


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Coverage at standard
cathode potential

Maximum Coverage
observed

a pllllflR^ pV⅛^VVI<

A P ∣L g f pWpk≡

APL lpS FRGSLP K⅛^lγλΛ:

A P L pS ∣FlP^∣G⅛1lL P1K1S1γVk

A PlL g lF ∣R G pS L P K1S1Y1V1K

APLgf   ⅛1 P1K1SiY1V1K

ApLLg|FpGSLpK pS1Y1vV;

a p L s f lr⅛⅛l p"k 1p1K

A plL^pS F R G pS L P K1S1Y1V1K

APL S.F.RlG⅛L P1K1S1γV1K

L LL     L

A p1L^pS F R G S L P K pS1Y1V1K

APL oS,Fl R⅛⅛L PiK1S1Y1V1K

L LlL

AP∣Lg∣Ff G pS L P K pS1Y1V1K

A P LI F R⅛^J,S1L P1K1pS1Y1V1K

A PlL S F R G pS L P K pS1 Y1V1K

A p L SlFlR1G1pS1L P1K1pS1Y1V1K


Figure 2.

Summary of fragments observed following ECD of doubly-charged precursor ions at
‘standard’ cathode potential and at the cathode potential which gave greatest sequence
coverage.


Published as: JAm SocMass Spectrom. 2008 September ; 19(9): 1263-1274.




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