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6


О 2     4     6     8    10    12

z∕σ


z∕σ

Figure 5.9: Symmetric segment density profiles of the A block (solid black curve) and
B block (dashed black curve) of the copolymer for (a) H = 9σ, (b) H = 10.6σ, (c) H =
13σ, and (d) H = 15σ. For the diblock copolymer, N = 8 and e∕kT = 0.289. For surfaces,
tw∕kT = 0.3.


Os             — Os         = ∏

û bmin, anti—symmetric     min,symmetric

For the earlier case with ew∕kT = 0.1,       = 0.2101 and ^minfanti-symmetric ~

^min,symmetric = 0∙2048. Hence, calculating just the free energies of symmetric phases

137



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