The name is absent



where, y^ntact[{Pa(rι)}] ɪɛ the cavity correlation function of hard sphere fluid at con-
tact approximated to its bulk value at the weighted density,
ps^9(pci) — ^ Jjrι-r2∣<σ. ⅛2∕z(es(r2),
AEX'hs is (-]∙ιe excess free energy due to the excluded volume of the segments (hard
sphere repulsions), and
Aex-'m is the excess free energy due to the long range at-
tractions between the segments, ʃɪ,ɑ and /2,« are multiple integrals solved using the
following recurrence,

Λ,α(r) = y^-iHexp^i^-^^rOlA^-^^r^r)*',  (6.3)

ʃi,i(r) = 1,                                                                   (6.4)

and

2,α(r) = y,2,α+ι(r')exp[Z>α+ι(r')-^f1(r')]∆(α-α+1)(r,r')dr',    (6.5)

2,m(r) = 1,                                                               (6.6)

where,

Δ-'(r1, r2) = ⅛∙[eχp(⅜0)l5dri.~⅛.Γ° i - lb"°'(r1, r2).      (6.7)

4π(σaa )∙i

K is a constant geometric factor that depends upon the associating volume, and ε0
is the association energy. In the limit of complete association, eɑ ~→ ∞∙ Note that
we can drop the Kexp(∕Jεo) term in the expressions for ∆(z,
j),s since they cancel out
the same terms in the bulk chemical potential.

In the case of grafted polymer chains, one of the end segments is physically/chemically

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