Chapter 4
Table 4.4 Equilibrium of surface reactions
Reaction |
K |
-aioh; -aioh+h+ |
[A1OH]¾(H*) ⅛ *^l∙ = [aioh;j e |
-AlOH f÷-AlO+H+ |
[A10 ]⅞(H>) ⅜ *,' [A10H] |
-SiOHj f≡ -SiOH + H+ |
[S1OH]¾(H)⅜ |
-SiOH -SiO+ H+ |
κ ,[SiO-⅛(H+) -⅜ |
-AO +Ca2+ f≡ -AOCa+, A: Al/ Si |
_ [ AOCa+] ʌɛa - 2eζ [AO^]αi(Ca2+)e kτ |
-AO’ +Mg2+ ɔ -AOMg+, A: Al/ Si |
_ [A0Mg+] ÆMg - 2eζ _________[AO^]αd(Mg2+)c ir |
-AOH+ +HSiOj -AOH2HSiO3, A: Al/ Si |
_ [AOH2HSiO3] ʌ HSiO3 — eζ [AOH2 ]ab (HSiOj)Cir |
-AOH2 +H3SiOj -AOH2H3SiO4, A: Al/ Si |
_ [AOH2H3SiO4] AH3SiO4 - eζ [AOH2 ]ab (H3SiO4 ')ekτ |
-AOH2 +HCOj f≡ -AOH2HCO3, A: Al/ Si |
_ [AOH2HCO3] aHCO3 — eζ [AOH2 ]ab (HC0j)βir |
-AOHj+SO4^ -AOH2SO;, A: Al/ Si |
_ [AOH2SO4] λS04 - 2eζ [A0H⅜ (SO2)Cir |
-AOH2 +L3^ -AOH2L2', A: AV Si, Lxitrate |
_ [AOH2L2] ʌb - 2eζ [A0H+]¾ (L3)cir |
115
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