Chapter4
Table 4.6 Effective diameter of the hydrated ions [26]
Ion |
a (nm) |
Ion |
a (nm) |
H+ |
0.9 |
SiO44' |
0.4 |
OH |
0.35 |
SO42' |
0.4 |
HCO3' |
0.4 |
H2L' |
0.35 |
CO32' |
0.45 |
HL2' |
0.45 |
*HSiO3' |
0.4 |
0.5 | |
*SiO32' |
0.4 |
Ca2+ |
0.6 |
H3SiO4' |
0.4 |
Mg2+ |
0.8 |
H2SiO42' |
0.4 |
**CaL' |
0.35 |
HSiO43' |
0.4 |
**MgL' |
0.35 |
*Data obtained by the estimation using carbonate and sulfate ions as reference.
** Data obtained by the estimation using H2L' ion as reference. L represents
citrate.
Table 4.7 Calculated activity coefficients of ions in synthetic brine (1=0.0478 M)
Ions |
________Y________ |
Ion |
________Y________ |
H+ |
0.935 |
SiO44' |
0.250 |
OH |
0.915 |
SO42' |
0.707 |
HCO3' |
0.917 |
H2L' |
0.917 |
CO32' |
0.714 |
HL2' |
0.715 |
HSiO3' |
0.917 |
I? |
0.478 |
SiO32' |
0.707 |
Ca2+ |
0.732 |
H3SiO4' |
0.917 |
Mg2+ |
0.753 |
H2SiO42' |
0.707 |
CaL' |
0.915 |
HSiO43' |
0.459 |
MgL' |
0.915 |
117
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