arc, IOO A of current passes between them, creating a plasma which provides a
nucleating environment for CNTs. To this day, arc-discharge is still a preferred
method for ultra-high-quality CNTs if there is little concern about length, though
other methods have since surpassed it in producing much larger quantities.
In 1993, José-Yacamân et al. reported the first use of CVD for the expressed
purpose of synthesizing CNTs [13]. The CVD process generally involves the use of a
hydrocarbon gas which decomposes in a high temperature environment, producing
the feedstock carbon for CNT synthesis. When placed in a sufficient but not
excessive temperature environment (generally ~700 - 900 oC), catalyst particles of
certain transition metals will begin to consume any available carbon and initiate the
growth of CNTs. In this last-referenced work [13], acetylene was passed over a
substrate covered with iron particles in a 700 0C atmosphere, resulting in the
growth of CNTs up to 50 μm in-length. Shortly after, Endo et al. were able to initiate
the use of a vapor-phase catalyst to synthesize pyrolized CNT structures by adapting
a procedure similar to what is used to create vapor-grown carbon nanofibers
(VGCNFs) [14]. By passing benzene over a carbon block in a hydrogen-rich
environment at 1000 0C, highly-graphitic CNTs and CNT-Iike structures were
generated. CVD is also responsible for the high-pressure CO (HiPCO) growth
method developed by Nikolaev et al. in 1999, which has allowed for the large-scale
production ofSWNTs [15]. Due to its relative ease, there have been many variations
on the CVD synthesis of CNTs which have brought it to prominence as a simple, yet
effective method to produce large quantities of CNTs.
More intriguing information
1. Opciones de política económica en el Perú 2011-20152. Credit Markets and the Propagation of Monetary Policy Shocks
3. Spatial agglomeration and business groups: new evidence from Italian industrial districts
4. Anti Microbial Resistance Profile of E. coli isolates From Tropical Free Range Chickens
5. Are Public Investment Efficient in Creating Capital Stocks in Developing Countries?
6. News Not Noise: Socially Aware Information Filtering
7. The name is absent
8. The Complexity Era in Economics
9. The name is absent
10. ISSUES AND PROBLEMS OF IMMEDIATE CONCERN