KINETICS ON THE MICROBIAL SCALE
49
Z = "ACTIVATED" |
COUPLING ENZYME | |
( I ) |
R∣t∙∣ + z = |
(ZR)iti |
(2) |
Oi +(ZR)itl = |
∣Z0∣it∣ + Ri |
(3) |
∣zo∣itl+ p = |
IZPi + oitl |
(4) ∣ZP} * ADP = Z t ATP + H2O
FIG. 4- A POSSIBLE MECHANISM FOR PHOSPHATE
FIXATION IN THE ELECTRON TRANSPORT
PATHWAY
algebra of the kinetic relations. Clearly we are going to end up with a
large number of parameters “to be determined" in the expressions we
will derive, simply because of the large number of reactions and elemen-
tary steps. The usual objective of “fitting the data to the theory” and
evaluating the constants is obviously out of the question. The best we
hope for is a set of equations which we can subject to certain tests.
These will necessarily be of the plausibility type, i. e., can we find a set
of physically meaningful parameters such that the mathematical system
is a reasonable model of the living system.
In Figure 5 I outline the procedure for obtaining the rate equation for
ALL SYMBOLS NOW REPRESENT CONCENTRATIONS

(THE K,∙j ARE EQUILIBRIUM CONSTANTS)
<f∣>i ∙^{'⅛0lΦij- b⅛(o*⅛)
THE fij ARE FORWARD
rate constantsithe
b*j ARE REVERSE RATE
CONSTANTS
*(J0b∣i.∣l ∙ E°. (CONSTANT 1
,Rl,∣ ANOTHE CONSTANTS kij , 11∣ , Ц,, E°
(2) (rt)i .∑(fij(θJ)ijiRitl - bijRi (Jθ)ijit∣)
(⅞)j .∑uj(Jo)ijitl - bij(J)ij oitl I
AT STEADY STATE: (rι)i∙(⅞)∣∙ ( Γj )∣
CONSERVATION OF ENZYME i :(Ej) ♦ ),j ♦ •••
(3) r . f* (OiXRld) - b* (OjdXRi)
WHERE f*,b*∣ ARE FUNCTIONS OF (Aj).(O∣). R∣ .O1
FIG.5-RATE EQUATIONS ANO ALGEBRA FOR TYPICAL STEP IN A PATHWAY
More intriguing information
1. The name is absent2. Passing the burden: corporate tax incidence in open economies
3. Multi-Agent System Interaction in Integrated SCM
4. AJAE Appendix: Willingness to Pay Versus Expected Consumption Value in Vickrey Auctions for New Experience Goods
5. Commuting in multinodal urban systems: An empirical comparison of three alternative models
6. LOCAL PROGRAMS AND ACTIVITIES TO HELP FARM PEOPLE ADJUST
7. An alternative way to model merit good arguments
8. Dual Inflation Under the Currency Board: The Challenges of Bulgarian EU Accession
9. The name is absent
10. Ventas callejeras y espacio público: efectos sobre el comercio de Bogotá