correlation function for an inhomogenous hard sphere reference fluid, and Faa (rɪ, r2)
is the association Mayer-/ function given as
Fαα'(rι,r2) = [exp(∕3ε0 - /M>nd(rι, r2)) - 1],
(3.26)
where ε0 is the association strength and u^d ɪɛ t^ιe bonding potential. In the limit
of complete association, ʌ^(rɪ) → 0 and ε → ∞, leading to following simplifications,
a Kexp(0εo) f dr2Xg'(r2)psae,9(r2)yaa'(r1,r2)exp(-β^d(r1,r2))' '
Two approximations were made to obtain simple analytical expressions for X%,
• Each site reaches its vanishing limit at the same rate, i.e. X∩ (r2) ≈ ^(∏)∙
Thereby,
A'exp(∕3ε0)∕dr2p^(r2)yαα'(r1,r2)cxp(-∕3z√6χ'd(r1,r2))' ^ɜ'2^
• The inhomogeneous cavity correlation function, yaa (rɪ, r2) is approximated by
its bulk value (at contact) at a weighted density.
Using these approximations the final expression for ^εx=assoc js given as
/Mβx~∏ = / ⅛ι^p^(r1)^f-∣ln^'>,fc(σ^',[p^(rι)])
∙' q=1 a `
76
More intriguing information
1. GENE EXPRESSION AND ITS DISCONTENTS Developmental disorders as dysfunctions of epigenetic cognition2. Globalization, Redistribution, and the Composition of Public Education Expenditures
3. The name is absent
4. Connectionism, Analogicity and Mental Content
5. Existentialism: a Philosophy of Hope or Despair?
6. Nietzsche, immortality, singularity and eternal recurrence1
7. Why unwinding preferences is not the same as liberalisation: the case of sugar
8. Temporary Work in Turbulent Times: The Swedish Experience
9. Education and Development: The Issues and the Evidence
10. The name is absent