The name is absent



polymers from iSAFT. The pure component parameters used to calculate the surface
tension of these real components were regressed to their bulk phase behavior. The
study clearly demonstrates that both bulk phase behavior and interfacial properties
can be described within the single framework of iSAFT (with the same set of pa-
rameters for both the systems). The success of the theory motivates us to extend
it to more complex systems, like copolymers and polymer brushes. However, few
shortcomings in iSAFT prevent us from doing so.

0.25


0.2

0.05

0      5     10     15     20     25     30     35     40     45     50


(b)

Figure 3.3: (a) Comparison of the density profiles of a single 50-mer hard chain tethered
to a hard surface (at z — 0) from simulation (symbols) and iSAFT (solid line),
(b) Density
profile of a single 50-mer ideal gas chain tethered to a hard surface (at z = 0).


The approximations in iSAFT are most accurate for the average segment density of
homonuclear polymers. If the segments on the polymer are too dissimilar, the theory
becomes less accurate. Even for homonuclear polymers, iSAFT does not constrain

78



More intriguing information

1. On the Integration of Digital Technologies into Mathematics Classrooms
2. Evidence-Based Professional Development of Science Teachers in Two Countries
3. Declining Discount Rates: Evidence from the UK
4. The name is absent
5. Ultrametric Distance in Syntax
6. APPLICATIONS OF DUALITY THEORY TO AGRICULTURE
7. The name is absent
8. Human Rights Violations by the Executive: Complicity of the Judiciary in Cameroon?
9. TRADE NEGOTIATIONS AND THE FUTURE OF AMERICAN AGRICULTURE
10. The name is absent