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Chapter 4

potential change of kaolinite. But adding meta-silicate has smaller effect on pH
change than adding ortho-silicate. Adding 3.0×10'4 M Na2SiO3, pH of the brine
increases from 8.3 to 9.0. Adding 3.0×10^4 M Na4SiO4, pH of the brine increases
from 8.3 to 9.2. Equilibrium constants Кнэюз and
Kh3S∣O4 are 13.7 m3∕mol and 8.7
m3∕mol, respectively.

O

O With Ca/ Mg, experiment data
-----With Ca/ Mg,, fitted curve _

* No Ca/ Mg, experiment data
-------No Ca/ Mg, fitted curve

4 ʌ*

S,

^H3SiO4 “ θ'7

O
m3∕mol       *                -




140




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