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Chapter 4

M NaCl brine adding CaCI2 or MgCI2 at pH 6.5 were measured.

-AO' +Ca2+ z≠ -AOCa+, -AO +Mg2+ -AOMg+                    [4.37]

=  [ AOCa+]  =       [ AOCa+]

'^ [A0]α,(Ca2*) [Aθ]a√Ca')exp(-¾
kι

= [AOMg+] =      [A0Mg+]

M8 [a0^MmS2+) [AO⅛(Mg2+)exp(-¾
kT

σ0(Ca) = e([AOH+]-[AO']-[B']+[AOCa+])                            [4.40]

σ0 (Mg) = e([AOH+] - [AO ] - [B' ]+[A0Mg+ ])                            [4.41 ]

Here Kca and Kwg are surface adsorption equilibrium constants.

Figure 4.26 Kaolinite zeta potential in 0.05 M NaCI brine adding MgCI2 at pH 6.5

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